Dowman P. Varn and James P. Crutchfield
Santa Fe Institute
1399 Hyde Park Rd.
Santa Fe, NM 87501, USA
We analyze solid-state phase transformations that occur in zinc-sulfide crystals during annealing using a random deformation-faulting mechanism with a very simple interaction between adjacent close-packed double layers. We show that, through annealing, infinite-range structures emerge from initially short-range crystal order. That is, widely separated layers carry structurally significant information and so layer stacking cannot be completely described by any finite-range Markov process. We compare our results to two experimental diffraction spectra, finding excellent agreement.
D. P. Varn and J. P. Crutchfield
From Finite to Infinite Range Order via Annealing: The Causal Architecture of Deformation Faulting in Annealed Close-Packed Crystals ,
Santa Fe Institute Working Paper 03-07-045; http://arXiv.org/abs/cond-mat/0307296.